Cashew bagasse agricultural residue as adsorbent in the removal of toluene from the mixture oil and water

Authors

  • André Luís Oliveira Maia Universidade Federal Rural do Semi-Árido
  • Ricardo Henrique de Lima Leite Universidade Federal Rural do Semi-Árido
  • Francisco Klebson Gomes Santos Universidade Federal Rural do Semi-Árido

DOI:

https://doi.org/10.18378/rvads.v15i2.7594

Keywords:

Adsorption, Bioadsorbent, Hydrocarbon

Abstract

Improper disposal of contaminated water into the environment has caused serious environmental problems for water bodies and soils. In order to reduce this problem, laws were created imposing limits on the amount of substances present in water before being discharged into the environment. Toluene has a very high pollutant potential due to its flammable, toxic and carcinogenic properties and even low concentrations need to be treated before disposal or reuse. Among the techniques offered for wastewater treatment, adsorption, using agricultural materials, stands out, which besides promoting a high percentage of removal has a low cost and high biodegradability. In this sense, this work aimed to evaluate the efficiency of cashew bagasse as a natural adsorbent for the removal of toluene in aqueous solution. The tests were performed in batch. Cashew bagasse dissolved substances that interfered with reading on the spectrophotometer. For this reason, a preliminary study was performed, resulting in a corrective method that disregards the interference of bagasse in the reading of the concentration of aliquots. The results showed a 77% removal. It was also observed that the removal percentage was higher for tests with higher initial solution concentration. The experimental data were better suited to Langmuir adsorption model and with maximum adsorption capacity of 49.02 mg toluene.g-1 of bagasse.

Downloads

Download data is not yet available.

References

AGUILERA F.; MENDEZ J.; PASARO E.; LAFFON B. Review on the effects of exposure to spilled oils on human health. Jornal of Applied Toxicology, v. 30, p. 291-301, 2010. 10.1002/jat.1521.

BRINQUES, G. B. Adsorção de tolueno de solução aquosa em leito de carvão ativado em planta piloto. 2005. 133 f. Dissertação (Mestrado) - Curso de Engenharia Química, Universidade Federal do Rio Grande do Sul, Porto Alegre - RS, 2005.

HARRIS, D. C. Análise química quantitativa. Editora LTC, 9ª. Edição, ISBN: 9788521620426. Rio de Janeiro, 2012.

IBRAHIM, S.; WANG, S.; ANG, H. M. Removal of emulsified oil from oily wastewater using agricultural waste barley straw. Biochemical Engineering Journal, v. 49, p. 78-83, 2010. 10.1016/j.bej.2009.11.013.

KUNDU, P.; MISHRA, I. M. Removal of emulsified oil from oily wastewater (oil-in-water emulsion) using packed bed of polymeric resin beads. Separation and Purification Technology, v. 118, p. 519-529, 2013. 10.1016/j.seppur.2013.07.041.

LIM, T.; HUANG, X. In situ oil/water separation using hydrophobic–oleophilic fibrous wall: A lab-scale feasibility study for groundwater cleanup. Journal of Hazardous Materials, v. 137, p. 820-826, 2006. 10.1016/j.jhazmat.2006.03.008.

MELO NETO, R. R.; SANTOS, F. K. G.; LEITE, R. H. L.; NÓBREGA, G. A. S.; RIOS, R. B. Remoção de nitrato da água utilizando bagaço de caju quimicamente modificado. Revista verde de agroecologia e desenvolvimento sustentável, v. 8, p. 08-16, 2013.

MOHAMMED, J.; NASRI, N. S.; ZAINI, M. A. A.; HAMZA, U. D.; ANI, F. N. Adsorption of benzene and toluene onto KOH activated coconut shell based carbon treated with NH3. International Biodeterioration & Biodegradation, v. 102, p. 244-255, 2015. 10.1016/j.ibiod.2015.02.012.

SRINIVASAN, A.; VIRARAGHAVAN, T. Removal of oil by walnut shell media. Bioresource Technology, v. 99, p. 8217-8220, 2008. 10.1016/j.biortech.2008.03.072.

WAHI, R.; CHUAH, L. A.; SHOONG, T. S. Y.; NGAINI, Z.; NOUROUZI, M. M. Oil removal from aqueous state by natural fibrous sorbent: An overview. Separation and Purification Technology, v. 113, p. 51-63, 2013. 10.1016/j.seppur.2013.04.015.

WANG, D.; MCLAUGHLIN, E.; PFEFFER, R.; LIN, Y. S. Adsorption of oils from pure liquid and oil–water emulsion on hydrophobic silica aerogels. Separation and Purification Technology, v. 99, p. 28-35, 2012. 10.1016/j.seppur.2012.08.001.

Published

01-04-2020

How to Cite

MAIA, A. L. O.; LEITE, R. H. de L.; SANTOS, F. K. G. Cashew bagasse agricultural residue as adsorbent in the removal of toluene from the mixture oil and water. Revista Verde de Agroecologia e Desenvolvimento Sustentável, [S. l.], v. 15, n. 2, p. 178–182, 2020. DOI: 10.18378/rvads.v15i2.7594. Disponível em: https://www.gvaa.com.br/revista/index.php/RVADS/article/view/7594. Acesso em: 25 apr. 2024.

Issue

Section

INTERDISCIPLINARY

Most read articles by the same author(s)

1 2 > >>