Functionalization of SBA-15 with EDTA and its application in removing Ca2+ and Mg2+ ions from hard water

Authors

  • Vanessa da Silva Bezerra Marques Universidade Federal Rural do Semi-Árido
  • Andarair Gomes dos Santos Universidade Federal Rural do Semi-Árido
  • Ricardo Henrique de Lima Leite Universidade Federal Rural do Semi-Árido
  • Franciso Klebson Gomes Santos Universidade Federal Rural do Semi-Árido

DOI:

https://doi.org/10.18378/rvads.v15i3.7618

Keywords:

SBA-15 synthesis, EDTA functionalization, Adsorption, Ca2 and Mg2 .

Abstract

Poor management, changes in drinking parameters and drought subject many parts of the world to survival in the face of shortages of drinking water and the quality of drinking water needs to be assessed for adequate consumption. Hard water can lead to the buildup of mineral deposits in pipes and appliances that use water on a regular basis, affecting the performance and life cycle of these items. In addition, in the presence of soap, fatty acids formed an insoluble precipitate with calcium ions, making foam and cleaning difficult, as well as other problems generated by the high content of Ca2+ and Mg2+ ions present in water. The goal of this paper was to study the removal of Ca2+ and Mg2+ ions using SBA-15, a mesoporous material, functionalized with ethylenediaminetetraacetic acid and compared to its pure matrix. This adsorbent was tested in Ca2+ and Mg2+ ions solution with concentration of 250 mg.L-1 and pH = 9, varying the temperature in 25°C and 50°C. Mesoporous materials were synthesized by hydrothermal method and characterized by TG/DTG (Thermogravimetry and Derivative Thermogravimetry), XRD (X-Ray Diffraction) and BET (Brunauer, Emmett and Teller method). Adsorption results showed removal of up to 50% of the Ca2+ and Mg2+ ions in a short time, approximately 5 min.

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References

BARBOSA, C. S.; SANTANA, S. A. A.; BEZERRA, C. W. B.; SILVA, H. A. D. S. Remoção de compostos fenólicos de soluções aquosas utilizando carvão ativado preparado a partir do aguapé (Eichhornia crassipes): Estudo cinético e de equilíbrio termodinâmico. Química Nova, v. 37, n. 3, p. 447–453, 2014. 10.5935/0100-4042.20140066

CHONG, C. C.; THE, L. P.; SETIABUDI, H. D. Syngas production via CO2 reforming of CH4 over Ni-based SBA-15:Promotional effect of promoters (Ce, Mg, and Zr). Materials Today Energy, v.12, p.408-417, 2019. 10.1016/j.mtener.2019.04.001 .

DA’NA, E. Adsorption of heavy metals on functionalized-mesoporous silica: A review. Microporous and Mesoporous Materials, v. 247, p. 145–157, 2017. 10.1016/j.micromeso.2017.03.050.

DONG, B. B.; ZHANG, B. B.; WU, H. Y.; CHEN, X.; ZHANG, K.; ZHENG, X. C. Synthesis, characterization and catalytic evaluation of SBA-15 supported 12-tungstophosphoric acid mesoporous materials in the oxidation of benzaldehyde to benzoic acid. Materials Research Bulletin, v. 48, n. 7, p. 2491–2496, 2013. 10.1016/j.materresbull.2013.03.004 .

EZZEDDINE,Z.; GENER, I. B.; POUILLOUX, Y.; HAMAD, H.; SAAD, Z.; KAZPARD, V. Divalent heavy metals adsorption onto different types of EDTA-modified mesoporous materials: Effectiveness and complexation rate. Microporous and Mesoporous Materials, v. 212, p. 125–136, 2015. 10.1016/j.micromeso.2015.03.013.

FELLENZ, N.; ALONSO, F. J. P.; MARTIN, P. P.; FIERRO, J. L. G.; BENGOA, J. F.; MARCHETTI, S. G.; ROJAS, S. Chromium (VI) removal from water by means of adsorption-reduction at the surface of amino-functionalized MCM-41 sorbents. Microporous and Mesoporous Materials, v. 239, p. 138–146, 2017. 10.1016/j.micromeso.2016.10.012.

FERREIRA, G. D.; PARK, S. W. Sílicas porosas: métodos de síntese e caracterização. Escola Politécnica da Universidade de São Paulo. Trabalho de conclusão de curso para obtenção do título de graduado em Engenharia Química, 2012.

FIORILLI, S.; RIVOIRA, L.; CALÌ, G.; APPENDINI, M.; BRUZZONITI, M. C.; COISSON, M.; ONIDA, B. Iron oxide inside SBA-15 modified with amino groups as reusable adsorbent for highly efficient removal of glyphosate from water. Applied Surface Science, v. 411, p. 457–465, 2017. 10.1016/j.apsusc.2017.03.206.

FONSECA-CORREA, R. A.; MURILO-ACEVEDO, Y. S.; GIRALDO-GUTIÉRREZ, L.; MORENO-PIRAJÁN, J. C. Microporous and Mesoporous Materials in Decontamination of Water Process. Microporous and Mesoporous Materials, 2016. 10.5772/64393.

GÓMEZ, G.; BOTAS, J. A.; SERRANO, D. P.; PIZARRO, P. Hydrogen production by methane decomposition over pure silica SBA-15 materials. Catalysis Today, v. 277, p. 152–160, 2016. 10.1016/j.cattod.2015.12.007.

GUO, Y.; LIU, D.; ZHAO, Y.; GONG, B.; GOU, Y.; HUANG, W. Synthesis of chitosan-functionalized MCM-41-A and its performance in Pb (II) removal from synthetic water. Journal of the Taiwan Institute of Chemical Engineers, v. 71, p. 537–545, 2017. 10.1016/j.jtice.2016.12.033 .

GUZIK, A. F.; JADACH, B.; PIOTROWSKA, H.; MURIAS, M.; LULEK, J.; NOWAK, I. Synthesis and characterization of SBA-16 type mesoporous materials containing amine groups. Microporous and Mesoporous Materials, v. 220, p. 231–238, 2016. 10.1016/j.micromeso.2015.09.006.

HERRMANN, C. C.; KLEIN, G. Zeolite a for selective calcium removal from brackish water? Reactive Polymers, Ion Exchangers, Sorbents, v. 5, n. 3, p. 281–293, 1987. 10.1016/0167-6989(87)90236-4.

HUANG, J.; YE, MENG.; QU, Y.; CHU, L.; CHEN, R.; HE, Q.; XU, D.; Pb (II) removal from aqueous media by EDTA-modified mesoporous silica SBA-15. Journal of Colloid and Interface Science, v. 385, n. 1, p. 137–146, 2012. 10.1016/j.jcis.2012.06.054.

IQBAL, S.; YUN, J.-I. EDTA-functionalized mesoporous silica for the removal of corrosion products: Adsorption studies and performance evaluation under gamma irradiation. Microporous and Mesoporous Materials, v. 248, p. 149–157, 2017. 10.1016/j.micromeso.2017.04.028.

LACHOWICZ, J. I. ; DELPIANO, G. R.; ZANDA D.; PILUDU, MN. ENRICO SANJUST, E.; MONDUZZI. M.; SALIS, A., Adsorption of Cu2+ and Zn2+ on SBA-15 mesoporous silica functionalized with triethylenetetramine chelating agent. Journal of Environmental Chemical Engineering, v.7, p.103205, 2019. 10.1016/j.jece.2019.103205.

LEE, J. Y.; CHEN, C. H.; CHENG, S.; LI, H. Y. Adsorption of Pb (II) and Cu (II) metal ions on functionalized large-pore mesoporous silica. International Journal of Environmental Science and Technology, v. 13, n. 1, p. 65–76, 2016.

MAJDA, D.; NAPRUSZEWSKA, B. D.; ZIMOWSKA, M. Porosity of SBA-15 after functionalization of the surface with aminosilanes. Microporous and Mesoporous Materials, v. 234, p. 98–106, 2016. 10.1016/j.micromeso.2016.07.013.

MARCAL-SILVA, H.; DUARTE, F. V.; OLIVEIRA, A. L. G. Avaliação do abrandamento de água calcária utilizando hidróxido de cálcio e carbonatação. Águas Subterrâneas, v. 31, n. 4, p. 310-315, 2017. 10.14295/ras.v31i4.28871.

MARINOSKI, A. K.; RUPP, R. F.; GHISI, E. Environmental benefit analysis of strategies for potable water savings in residential buildings. Journal of Environmental Management, v. 206, p. 28–39, 2018. 10.1016/j.jenvman.2017.10.004

MERKACHE, R.; FECHETE, I.; MAAMACHE, M. 3D ordered mesoporous Fe-KIT-6 catalysts for methylcyclopentane (MCP) conversion and carbon dioxide (CO2) hydrogenation for energy and environmental applications. Applied Catalysis A: General, v. 504, p. 672–681, 2015. 10.1016/j.apcata.2015.03.032

MESTRE, A. S.; NABIÇO, A.; FIGUEIREDO, P. L.; PINTO, M. L. Enhanced clofibric acid removal by activated carbons: Water hardness as a key parameter. Chemical Engineering Journal, v. 286, p. 538–548, 2016. 10.1016/j.cej.2015.10.066.

MORITZ, M.; GESZKE-MORITZ, M. Amine-modified SBA-15 and MCF mesoporous molecular sieves as promising sorbents for natural antioxidant. Modeling of caffeic acid adsorption. Materials Science and Engineering C, v. 61, p. 411–421, 2016. 10.1016/j.msec.2015.12.093.

OLIVEIRA JUNIOR, H. S.; SILVA, P. C. M.; SILVA, C. L. C. Monitoramento e mapeamento das águas subterrâneas de abastecimento urbano do município de Mossoró-RN. Revista Brasileira de Geografia Física, v. 9, p. 1825–1835, 2016. https://doi.org/10.26848/rbgf.v9.6.p1825-1835.

POPA, A.; SASCA, V.; KISS, E. E.; NEDUCIN, R. M.; HOLCLAJTNER-ANTUNOVIĆ, I., Mesoporous silica directly modified by incorporation or impregnation of some heteropolyacids: Synthesis and structural characterization. Materials Research Bulletin, v. 46, n. 1, p. 19–25, 2011. 10.1016/j.materresbull.2010.10.003.

QIN, C.; WANG, R.; MA, W. Characteristics of calcium adsorption by Ca-Selectivity zeolite in fixed-pH and in a range of pH. Chemical Engineering Journal, v. 156, n. 3, p. 540–545, 2010a. 10.1016/j.cej.2009.04.006.

QIN, C.; WANG, R.; MA, W. Adsorption kinetic studies of calcium ions onto Ca-Selective zeolite. Desalination, v. 259, n. 1–3, p. 156–160, 2010b. 10.1016/j.desal.2010.04.015.

SANTHOSH, C.; VELMURUGAN, V.; JACOB, G.; JEONG, S. K. Role of nanomaterials in water treatment applications: A review. Chemical Engineering Journal, v. 306, p. 1116–1137, 2016. 10.1016/j.cej.2016.08.053.

SENNA, A. M.; BOTARO, V. R.; NOVACK, K. M. Síntese, caracterização e aplicação de hidrogel derivado de acetato de celulose e etilenodiaminotetracético (EDTA) como substrato de liberação controlada de fertilizantes NPK e retenção de água em solo. 125 f. Tese (Doutorado em Engenharia de Materiais) – Escola de Minas, Universidade Federal de Ouro Preto, Ouro Preto, 2015.

SHENG, X.; KONG, J.; ZHOU, Y.; ZHANG, Y.; ZHANG, Z. Direct synthesis, characterization and catalytic application of SBA-15 mesoporous silica with heteropolyacid incorporated into their framework. Microporous and Mesoporous Materials, v. 187, p. 7–13, 2014. 10.1016/j.micromeso.2013.12.007.

SILVA, C. R. P. DA; FONSECA, E. J. DA S.; SILVA, A. O. S. Encapsulamento da Maggiferina em sílica mesoporosa: síntese e caracterização. Tese (doutorado em Materiais) - Universidade de Alagoas. Centro de Tecnologia. Programa de Pós-Graduação em Materiais, Maceió, 2017.

SOLTANI, S.; RASHID, U.; AL-RESAYES, S. I.; NEHD, I. A. Recent progress in synthesis and surface functionalization of mesoporous acidic heterogeneous catalysts for esterification of free fatty acid feedstocks: A review. Energy Conversion and Management, v.141, p.183-205, 2017. 10.1016/j.enconman.2016.07.042.

THUNYARATCHATANON, C.; LUENGNARUEMITCHAIA, A.; CHAISUWANA, T.; CHENC, S. Y.; YOSHIMURA, Y. Synthesis and characterization of Zr incorporation into highly ordered mesostructured SBA-15 material and its performance for CO2 adsorption. Microporous and Mesoporous Materials, v. 253, p. 18–28, 2017. 10.1016/j.micromeso.2017.06.015.

WU, L.; WANG, H.; LAN, H. Adsorption of Cu (II)–EDTA chelates on tri-ammonium-functionalized mesoporous silica from aqueous solution. Separation and Purification Technology, v. 117, p. 118–123, 2013. 10.1016/j.seppur.2013.06.016.

ZHANG, K.; OSTRAAT, M. L. Innovations in hierarchical zeolite synthesis. Catalysis Today, v. 264, p. 3–15, 2016. 10.1016/j.cattod.2015.08.012.

ZHAO D.; FENG J.; HUO Q.; MELOSH N.; FREDRICKSON G. H.; CHMELKA B. F., STUCKY G. D. Triblock copolymer syntheses of mesoporous silica with periodic 50 to 300 angstrom pores. Science, v.279, n.80, p.548–552, 1998. 10.1126/science.279.5350.548.

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Published

01-07-2020

How to Cite

MARQUES, V. da S. B.; SANTOS, A. G. dos; LEITE, R. H. de L.; SANTOS, F. K. G. Functionalization of SBA-15 with EDTA and its application in removing Ca2+ and Mg2+ ions from hard water. Revista Verde de Agroecologia e Desenvolvimento Sustentável, [S. l.], v. 15, n. 3, p. 300–308, 2020. DOI: 10.18378/rvads.v15i3.7618. Disponível em: https://www.gvaa.com.br/revista/index.php/RVADS/article/view/7618. Acesso em: 20 jun. 2024.

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